Coal and Petroleum


   
 
Nomenclature of Hydrocarbons
Nomenclature is the system of naming. With the existence of innumerable compounds of carbon, it has become necessary to follow a universal, rational system of naming. Such a system has been evolved by International union of pure and applied chemistry (IUPAC). By following this system, we can eliminate the confusion that arises due to usage of common names or trivial names.
 
Nomenclature of straight chain hydrocarbons
 
The IUPAC name of a straight chain hydrocarbon is divided into two parts:
 
i. Word root
 
ii. Suffix
 
Word root
 
Word root determines the number of carbon atoms in the compound. The word roots for compounds having five or more carbon atoms are derived from Greek numbers.
 

 
Suffix
 
To determine the nature of the bond (single, double or triple) between the carbon atoms, primary suffixes are used.
 
 
 
Nomenclature of saturated hydrocarbons (alkanes)
 
In the IUPAC nomenculature, alkanes end with '-ane'
 
 
Nomenclature of unsaturated hydrocarbons
 
Alkenes
 
In the IUPAC nomenclature, alkenes end with '-ene'
 
 
Alkynes
 
In the IUPAC nomenculature, alkenes end with '-yne'.
 
 
 
 
     
   
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