Molecules of Compounds


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A molecule of a compound consists of two or more atoms of different elements joined together in a fixed ratio.

Examples: CuSO4 contains Cu - 1 atom, S - 1 atom, O - 4 atoms

A chemical formula represents the composition of a molecule of the substance in terms of the symbol of the elements present in the molecule. It is also called molecular formula.

Molecular mass

The molecular mass of a substance is the relative mass of its molecule as compared with the mass of a12C atom taken as 12-units. It indicates the number of times, one molecule of the substance is

Table 2: Molecular Formulae of important Acids

 Acid  Molecular Formula
 Hydrochloric acid  HCl
 Nitric acid  HNO3
 Sulphuric acid  H2SO4
 Phosphoric acid  H3PO4
 Acetic acid  CH3COOH
 Carbonic acid  H2CO3
 Sulphurous acid  H2SO3
 Nitrous acid  HNO2

Table-3: Molecular formulae of important bases

 Base  Molecular Formula
 Ammonium hydroxide  NH4OH
 Sodium hydroxide  NaOH
 Potassium hydroxide  KOH
 Calcium hydroxide  Ca(OH)2
 Magnesium hydroxide  Mg(OH)2
 Aluminium hydroxide  Al(OH)3
 Zinc hydroxide  Zn(OH)2
 Iron (II) hydroxide  Fe(OH)2
 Iron(III) hydroxide  Fe(OH)3
 Copper(II) hydroxide  Cu(OH)2

Molecular formulae of important salts

Table- 4: (A) Molecular formulae of Oxides

 Oxide  Molecular Formula
 Sodium Oxide  Na2O
 Potassium Oxide  K2O
 Calcium Oxide  CaO
 Magnesium Oxide  MgO
 Aluminium Oxide  AlO
 Zinc Oxide  ZnO
 Iron(II) Oxide  FeO
 Iron(III) Oxide  Fe2O3
 Lead(II)Oxide  PbO
 Lead(IV)Oxide  PbO2
 Copper Oxide  CuO
 Mercury Oxide  HgO
 Carbonate or Hydrogen carbonate  Molecular Formula
 Sodium Carbonate  Na2CO3
 Sodium hydrogen carbonate  NaHCO3
 Potassium carbonate  K2CO3
 Potassium hydrogen carbonate  KHCO3
 Calcium carbonate  CaCO3
 Calcium hydrogen carbonate  Ca(HCO3)2
 Magnesium carbonate  MgCO3
 Magnesium hydrogen carbonate  Mg(HCO3)2
 Aluminum carbonate  Al2(CO3)2
 Zinc carbonate  ZnCO3
 Iron(II) carbonate  FeCO3
 Lead(II) carbonate  PbCO3
 Tin(II) carbonate  SnCO3
 Copper(II) carbonate  CuCO3

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Calculation of molecular mass

Molecular mass is equal to sum of the atomic masses of all atoms present in one molecule of the substance.

Example:

H2O

Mass of H atom = 1

Mass of 2H atoms = 2

Mass of O atom = 16

Molecular mass = 2 + 16 = 18gms

Gram molecular mass

Molecular mass expressed in grams is numerically equal to gram molecular mass of the substance.

Molecular mass of O2 = 32

Gram molecular mass of O2 = 32gms

Significance of molecular formula

  • It represents name of the substance
  • It represents one molecule of substance
  • It gives the names of all the elements present in one molecule of the substance. It also gives the number of atoms of each element present.
  • It represents a definite mass and refers to the presence of 6.023 x 1023 molecule.

Relative atomic mass

It is very difficult to accurately weigh the number of atoms as they are extremely light and small and they cannot be seen. Indirect methods have been utilized to determine the absolute mass of an atom.

Relative atomic mass

Relative atomic mass of elements

Mass of a hydrogen atom = 16.735 x 10-24g

Mass of a oxygen atom = 26.565 x 10-24g

We all know that atoms are too small and weigh too little to express their masses in grams or kilograms. Therefore it was agreed upon that the mass of a particular atom should be considered as a standard unit and the masses of other atoms to be related to the standard. The resulting masses are considered to be relative atomic masses as they are relative to the standard.

Oxygen and hydrogen were initially chosen as the standard units. But later C12 atom [carbon isotope] was considered the standard for comparison with other atoms or molecules.

Relative atomic mass (RAM) of an element is the number of times one atom of an element is heavier than 1/12 the mass of an atom of carbon [C12].

Gram atomic mass is the relative atomic mass of an element expressed in grams.


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