Electrolytes and Electrolysis


   
 
Summary
The energy associated with the moving charges is called current electricity.
 
Electrolysis is the process of decomposition of an electrolyte as a result of passage of electricity to its molten state or aqueous solution.
 
In an electro-chemical cells (voltaic cell) chemical energy is converted into electrical energy.
 
Oxidation and reduction are complimentary processes and always occur simultaneously in an electrochemical cell.
 
Chemical process involving oxidation and reduction is called redox reaction.
 
A redox reaction involves transference of electrons from reducing agents to oxidizing agents.
 
Passage of electricity through a metal or graphite is different from passage of electricity through aqueous solution of electrolyte in that during the process the metal does not decompose but the electrolyte decomposes.
 
The ions that are lower in the electrochemical series get discharged in preference to the ones above them.
 
During electrolysis the metals and hydrogen are set free at the cathode and they are said to be electropositive. Non-metals are set free at the anode and are said to be electronegative.
 
Oxidation number is a residual charge, which an atom of the element appears to have when other atoms from the molecule are removed as ions by counting the electrons with more electronegative element.
 
 
     
   
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