Electrolytes and Electrolysis


   
 
Other Classes of Electrolytes (Acids, Bases and Salts)
Acid, bases and their salts are all compounds that can undergo electrolytic dissociation. Hence these substances can also be classified as electrolytes.
 
Acids
 
"An acid is a substance, which on dissolving in water forms hydrogen or hydronium ions, as the only positive ions."
 
 
Strong acid
 
An acid that gets completely or almost completely dissociated or ionised into ions is categorized as a strong acid. Greater the number of hydrogen ions or hydronium ions dissolved in water, the stronger is the acid.
 
For e.g., concentrated (99%) sulphuric acid behaves like a weak electrolyte, as it has very few hydronium ions in it. But when added to water, it becomes a dilute acid. Under these conditions it produces large number of hydronium ions, it behaves like a stronger electrolyte. Thus dilute sulphuric acid is a "stronger" electrolyte as compared to concentrated sulphuric acid.
 
 
 
 
A "strong acid" differs from a "concentrated acid". Concentration indicates the proportion of the acid in the aqueous solution. Whereas "strength" of an acid indicates the hydronium ion concentration in the solution.
 
 
Weak acid
 
An acid which dissociates very feebly in water and whose molecules mostly remain in the undissociated form is categorized as a weak acid. It behaves as a weak electrolyte.
 
 
 
Base
 
"A base is an electrovalent compound, which on dissolving in water, dissociates into a positively charged metal ion or ammonium ion and a negatively charged hydroxyl ion."
 
Strong base
 
A base that dissociates completely or almost completely into ions in aqueous medium is called a strong base. Greater the number of hydroxyl ions in water, the stronger it is as a base and an electrolyte.
 
 
 
Weak base
 
A base that dissociates only partially into ions in aqueous medium is called a weak base. It behaves as a weak electrolyte.
 
 
Salt
 
"A salt is an electrovalent compound, made up of a positive ion other than a hydrogen ion (H+) and a negative ion, other than a hydroxyl ion (OH-). When dissolved in water, it dissociates into free mobile ions." Such salts thus behave as electrolytes. They can be strong or weak electrolytes depending on the degree of dissociation.
 
 
 
 
 
     
   
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