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Chemistry IV
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Chemical Kinetics
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Parallel Reactions
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A parallel reaction is of the following type in which a reactant A transforms itself to two different products B and C.
The rate expressions for the reactant and the products are,
The solution to these equations are as follows
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Chemical Kinetics
Introduction
Reaction Rates- Rate of a Chemical Reaction
Concentration of Reactants
Surface Area of a Solid Reactant or Catalyst
Rate of a Reaction
Expressions of Rates of Reaction
Calculation of Average Rate of Reaction
Instantaneous Rate
Experimental Determination of Rate of Reaction
Rate Law Expression
Order of a Reaction
Zero Order Reaction
First Order Reaction
Second Order Reaction
Fractional Order Reaction or Complex Order
Pseudo First Order Reaction
Methods to Determine Order of a Reaction
Graphical Method of Order Determination
Initial Rate Method
Isolation Method
Half Life of a Reaction
Calculation of Order of a Reaction
Radioactive Dating
Relationships for Zero order, First order and Second order Reactions
Concept of Activation Energy
Energy and Orientation Barriers to Reactions
Energy Barrier
Orientation Barrier
Transition State Theory
Kinetic Stability of Fuels
Mechanism of Reaction
Molecularity
Series Reactions (First Order)
Reactions Involving A Slow Step
Reactions Where The Steady State Approximation Is Valid
Reactions where The Intermediate is in Equilibrium with the Reactant
Parallel Reactions
Catalysis
Autocatalysis
Photochemical Reactions
Photosensitization
Photosynthesis
Conclusion
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