Chemical Kinetics

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Second Order Reaction
Example 6:
 
Nitrogen dioxide (NO2) gas reacts with fluorine gas (F2) to give nitrosyl fluoride. The chemical reaction is given by the equation.
 
 
The reaction has the rate law as:
 
rate (r) = k [NO2] [F2]
 
The rate has order one with respect to nitrogen dioxide concentration and fluorine concentration and the overall order is (1 + 1) which is two.
 
 
fig 6.6 - A comparison of first order and second order reactions
 
The above figure depicts the change of concentration of second order reaction with only one reactant, that is, a reaction of the type A P where the rate law is rate r = k [A]2.
 
 
     
   
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