Zero Order Reaction


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Example 4:

Ammonia (NH3) gas decomposes over platinum catalyst to nitrogen gas (N2) and hydrogen gas (H2). The chemical reaction is as follows:

example for zero order kinetics

The reaction follows zero order kinetics. Therefore the rate law is rate r = k[NH3]o

For a zero order reaction the concentration versus time profile is linear and the rate of reaction versus time has the profile.

Concentration versus time profile for a zero order reaction

fig 6.4(a) - Concentration versus time profile for a zero order reaction

Rate of reaction versus time for a zero order reaction

fig 6.4 (b) - Rate of reaction versus time for a zero order reaction


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