Nuclear Chemistry Summary


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  • Radioactivity

Spontaneous emission of active rays by certain unstable elements.

  • Three types of radiations are:

(i) Alpha particles He2+ ion (Helium nuclei).

(ii) Beta - rays - consist of electrons.

(iii) Gamma - rays - High energy electromagnetic rays.

  • Emission of alpha particle reduces the atomic number by 2 and the mass number by 4. b- emission advances the atomic number by one unit without changing the mass number. Emission of a - rays affects neither the mass nor the atomic number.
  • N/P Ratio - Stable nuclei has N/P ratio in the range 1 - 1.6.
  • For a particular radioactive decay process, the number of nuclei decaying in a short period of time is proportional to the number present and is independent of physical and chemical conditions surrounding the atom. Decay process follows First order kinetics.

formula for decay constant

  • Half-life period of a nuclide

The time taken to reduce the number of nuclei to one half the original.

formula for half life period
  • 3 natural decay series - decay by emission of and emission
1st series starts with 232Th ends with 208PB

2nd series starts with 238U end with 206Pb

3rd series starts with 235U ends with 207Pb

4th artificial series starts with 237Np ends in 209Bi.

  • Artificial radioactivity

Nuclear changes can be brought about by bombardment of nuclei with accelerated particles like neutrons, deuterons and protons.

  • A particularly important process for the production of artificial radioactive isotope is the (n, g) reaction, which is applied to synthesize new elements.
  • Units of Activity - 1 Becqueral (Bq) = 1 disintegration per second
Curie (Ci) = 3.7 x 1010 dis/sec

= 3.7 x 1010 Bq.

  • Nuclear Fission

Heavy nuclei can break up into two fragments of intermediate size and a few neutrons, the loss in mass occurs which releases vast amount of energy.

  • Nuclear Fusion

Light nuclei fuse together with mass losses, which produce large quantities of energy. Fusion reactions require high temperatures to be initiated. Hence they are called thermonuclear reactions.

  • Radioisotopes find applications as tracers in analytical uses, for dating the age of minerals, rocks etc. and in the field of medicines.


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