The basic three - level scheme for laser operation.
Metastable state E2 has a greater population than the ground state E1
From E3, the atoms decay rapidly to a state of energy E2. For lasing to occur, this state must be metastable; that is, it must have a relatively long mean life against decay by spontaneous emission. If conditions are right, state E2 can then become more heavily populated than state E1, thus providing the needed population inversion. A stray photon of the right energy can then trigger an avalanche of stimulate emission events, resulting in the production of laser light. A number of lasers using crystalline solids (such as ruby) as a lasing material operate in this three-level mode.

