and ethyne


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Ethyne
Ethyne is an unsaturated hydrocarbon with a triple bon..
Preparation of Ethyne (Acetylene)
Ethyne (acetylene) is the simplest alkyne and can be obtained by the following method..
Structure of ethyne (acetylene)
sp hybridization of carbon orbitals Ethyne (acetylene) can be described by the molecular formula C 2 H 2 . As each carbon atom in this molecule has two points of attachments, each carbon atoms in ethyne (acetylene) is sp hybridized. sp hybridization of carbon orbitals The two 'sp' hybrid orbitals are oriented..
Addition reactions
Ethyne undergoes addition reactions to give saturated compound..
Alkynes
These hydrocarbons contain at least one carbon-carbon triple bond. For example, ethyne, propyn..
Physical Properties of Alkynes
The first three members (ethyne, propyne and butyne) are colourless and odorless gases. Due to the presence of phosphine as an impurity ethyne (acetylene) has garlic smell. The next eight members are liquids, and higher members are solids under normal conditions of tempera..
Oxidation
ethyne oxidises to oxalic acid Oxidation of alkynes gives mono or dicarboxylic acids. For example, Alkaline KMnO4 oxidises ethyne to oxalic acid. oxalic acid(ethanedioic acid) With chromic acid, ethyne gives acetic acid. ethyneethanoic acid(acetylene)(acetic acid) Homologues of ethyne..
Addition of hypochlorous acid
formation of dichloroethanal from ethyne Alkynes react with hypochlorous acid according to the Markownikoff's rule. dichloroethanal In the presence of peroxides the addition of HBr takes place according to the anti-MarkowniKoff's rul..
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