positive deviation of ideal gas behaviour


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Ideal Gas Equation
ideal gas equation ). This means that 'K' is directly proportional to the number of moles, 'n', i.e., K n or K = nR, where 'R' is the universal gas constant of proportionality. The value of 'R' is same for all gases. However, the numerical value of 'R' varies with the units in which pressure and volume are ..
Non-ideal Solutions
In general, most of the solutions deviate from ideal behavior. There are two types of deviations, positive deviation and negative deviations. Such solutions are called non ideal solution..
Effect of pressure
All gases are known to exist as real gases and show ideal behaviour only to some extent under certain conditions. When PV = nRT for ideal gases, then the ratio..
The First Law of Thermodynamics
cylinder piston We have seen that heat is just a form of energy. A system can be given energy either by supplying heat to it (by placing it in contact with a hotter object) or by doing mechanical work on it. Consider an ideal gas in a cylindrical container, fitted with a piston as shown in the ..
Conversion from Celsius to Kelvin and vice versa
To convert Celsius scale to Kelvin scale, add 273 to the Celsius temperature. 32 o F = 0 + 273 = 273 K 212 o F = 100 + 273 = 373 K -459.4 o F = - 273 + 273 = 0 K To convert Kelvin scale to Celsius scale, subtract 273 from the Kelvin scale. 0 K = 0 - 273 = - 523.4 o F 273 K = 273 - 273 = 32 o..
Optics Summary
Summary - Ray optics is also called geometrical optics as it uses the geometry of straight-line paths (rays) to explain the optical phenomena. Ray optics, infact, is the limiting case of wave optics. This means for most practical purposes, we can ignore the deviation from straight-line pa..
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