tetrahedral void in simple cube


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Tetrahedral Voids
Tetrahedral void A simple triangular void in a crystal is surrounded by four spheres. fig 2.11 - A unit cell of simple cubic packing fig 2.11 - (a) Tetrahedral void..
Types of Voids
Tetrahedral void Tetrahedral Voids - A simple triangular void in a crystal is surrounded by four spheres. fig 2.11 - A unit cell of simple cubic packing fig 2.11 - (a) Tetrahedral void..
Derivation of the Relationship Between Radius r of the Tetrahedral Void and the Radius R of the Atoms in the Close Packing
tetrahedral void in cube Derivation of the Relationship Between Radius r of the Tetrahedral Void and the Radius R of the Atoms in the Close Packing. A tetrahedral void may be represented in a cube as shown in the below figure. fig 2.12 - Tetrahedral v..
Points to Remember
Number of octahedral voids = Number of atoms present in the close packed arrangement Number of tetrahedral voids = 2 x Number of octahedral voids = 2 x Number of ato..
Suggested solution:
B atoms form CCP structure Number of octahedral voids = Number of B atoms Number of tetrahedral voids = 2 x Number of B atoms. Since the number of A atoms = 2 x Number of B atoms therefore they occupy all of tetrahedral voids. Coordination number o..
Main features
Each Ca 2 + ion is present at the corners and the face centers (F.C.C. or C.C.P.). F - ions are present in all the tetrahedral voids. Each Ca 2 + is surrounded by 8F - where as each F - is surrounded by 4Ca 2 + so it has 8:4 co-ordination. Number of Ca 2 + ..
Water
Water is the only substance that can exist simultaneously in all the three states of matter, i.e., solid, liquid and gaseous on this earth,. A simple experiment shows the existence of all these three states together. Take a glass half packed with ice cubes and cover it. Th..
Ferrites
They are compounds having the general formula AFe 2 O 4 where A is a divalent cation like Mg 2 + or Zn 2 + . They are obtained from Fe 3 O 4 by replacing Fe 2 + by divalent cations. These belong to a category with a general formula AB 2 O 4 where A is a divalent cation and B is a trivalent..
Zeolites
Zeolites are microporous aluminosilicates of general formula M x / n [AlO 2 ] x [SiO 2 ].mH 2 O and may be considered as open structures of silica in which aluminium has been substituted in a fraction x / (x+y) of the tetrahedral sites. The negative charge of the aluminosilicate framework..
Solid State
In solids, atoms or molecules are closely packed and the intermolecular space or void is minimum. The average distance between particles is of the order 10 -8 cm; consequently, solids are almost incompressible. In addition, the intermolecular attraction in solids is quite high and for tha..
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