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VSEPR Theory
Valence Shell Electron Pair Repulsion (VSEPR) Theory - The VSEPR theory, proposed by R.J.Gillespie and R.S. Nyholmm in 1957, is based on the repulsions between the electron-pairs in the valence-shell of the atoms in the molecule. It was developed to predict t..
Postulates of Kinetic Theory
All gases are made up of large number of minute particles called molecules. Large distances separate the molecules so that the actual volume of the molecules is negligible as compared to the total volume of the gas. The molecules are in a state of constant rapid motion in all directions, co..
Predicting the shape of molecules on the basis of VSEPR theory
To use this theory for predicting the shapes of molecules, the number of electron pairs (both, shared and lone pairs) is simply counted. This is illustrated by taking a typical molecule of the type AB n . 'A' is the central atom, 'B' atoms are bonded to 'A' by single covalent bonds (sing..
Bohr's Theory of Hydrogen Atom
Niels Bohr suggested that the problem about hydrogen spectrum can be solved if we can make some assumptions. According to classical theory, the frequency of the electromagnetic waves emitted by a revolving electron is equal to the frequency of revolution. As the electrons radiate energy, ..
Huygen's Wave Theory
Huygen's Principle - Christian Huygen Huygen proposed a hypothesis for the geometrical construction of the position of a common wavefront at any instant during the propagations of waves in a medium. The postulates are: Every point on the given wavefront called 'primary wavefront' acts as ..
Huygen's Principle - Christian Huygen Huygen proposed a hypothesis for the geometrical construction of the position of a common wavefront at any instant during the propagations of waves in a medium. The postulates are: Every point on the given wavefront called 'primary wavefront' acts as ..Theory of Electrolytic Dissociation
The chief postulates of the ionic theory or theory of electrolytic dissociation are as follows: On dissolving in water an electrolyte, breaks up into free cations and anions. The energy associated with moving charges is called current or electricity. The ions carry an ..
Valence Bond (VB) Theory
Main Postulates - I) The metal ligand bond arises by donation of pair of electrons by ligands to the central metal atom. II) To accommodate these electrons the metal ion must possess requisite number of vacant orbitals of equal energy. These orbitals of the metal atom undergo hybridisatio..
Dalton's Atomic Theory
John Dalton provided a simple theory of matter to provide theoretical justification to the laws of chemical combinations in 1805. The basic postulates of the theory are: All substances are made up of tiny, indivisible particles called atoms. Atoms of the same element a..
Quantum Theory of Covalent Bond
Although the Lewis structures give an idea of the valence electrons around the atom, in reality it does not precisely locate the position of the electrons in the chemical bond. The behaviour of electrons in molecules and compounds is made by the valence bond theory in terms of the quantum..
Problem
10. Predict the shapes of the following molecules using the valence shell electron pair repulsion (VSEPR) theory. AsF 5 , HgBr 2..
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