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Orbital Wave Functions and Shapes of Orbitals
According to wave mechanics, orbitals are described by wave functions known as orbital wave functions. These orbital wave functions can be represented as a product of two functions: (i) Radial wave function and (i..
Orbital Wave Functions and Shapes of Orbitals
According to wave mechanics, orbitals are described by wave functions known as orbital wave functions. These orbital wave functions can be represented as a product of two functions: (i) Radial wave function and (ii) Ang..
Molecular Orbital Theory
Molecular orbital theory was proposed by F. Hund and R.S. Mulliken in 1932. The basic idea of molecular orbital theory is that atomic orbitals of individual atoms combine to form molecular orbitals. The electrons in molecules are present in the mole..
Atomic Orbitals
Electrons cannot exist at a particular point or in a well-defined orbit (path), according to the above new approach called wave mechanics. This led to the concept of 'most probable regions'. We talk about 'certain regions in space around the nucleus called atomic orbi..
Concept of Orbital
According to wave mechanics, we cannot simply say that the electron exists at a particular point but we talk about certain regions in space around the nucleus where the probability of finding the electron is maximum. Such regions are expressed by mathematical expressions and are called ..
Atomic Orbitals
Electrons cannot exist at a particular point or in a well-defined orbit (path), according to the above new approach called wave mechanics. This led to the concept of 'most probable regions'. We talk about 'certain regions in space around the nucleus called atomic orbitalsh..
Probability Picture of Electrons and Concept of Atomic Orbital (Wave Mechanical Treatment)
The wave character of an electron and uncertainty in its position and momentum gave a serious blow to Bohr's model of an atom. According to Bohr, the electrons revolve around the nucleus in certain well-defined circular orbits. But the idea of uncertainty in position and v..
Intensity of a Wave
Intensity of a Wave - In all progressive waves, energy travels through the medium in the direction in which the wave travels. Each particle of the medium has energy of vibration and passes energy on to succeeding particles. In simple harmonic motion, the energy of the ..
Intensity of a Wave - In all progressive waves, energy travels through the medium in the direction in which the wave travels. Each particle of the medium has energy of vibration and passes energy on to succeeding particles. In simple harmonic motion, the energy of the ..Outer orbital complex
When the complex formed involves use of outer nd - orbitals sp 3 d 2 . It is called outer orbital complex. It has a large number of unpaired electrons. Example: [CoF 6 ] 3 - , [MnF 6 ] 3 - , [Fe F 6 ] 3 - because F - is a weak ligand..
Molecular Orbital Theory
Molecular orbital theory was proposed by F. Hund and R.S. Mulliken in 1932. The basic idea of molecular orbital theory is that atomic orbitals of individual atoms combine to form molecular orbitals. The electrons in molecules are present in th..
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