In plants, breakdown of substances is much slower than in animals. Hence accumulation of waste is much slower and there are no special organs of excretion. Green plants in darkness or plants that do not contain chlorophyll produce carbon dioxide and water as respiratory waste products. Carbon dioxide released during respiration gets utilized during photosynthesis.
Oxygen itself can be thought of as a waste product generated during photosynthesis. Plants can get rid of excess water by transpiration.
Waste products may be stored in leaves that fall off. Other waste materials that are exuded by some plants — resins, saps, latexes, etc. are forced from the interior of the plant by hydrostatic pressures inside the plant and by absorptive forces of plant cells. Plants also excrete some waste substances into the soil around them.